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Additionally, although true allergies to glycine are exceedingly rare, any prior hypersensitivity reaction to glycine or to components of the formulation would contraindicate its use

Endothelium microenvironment sensing leading to nitric oxide mediated vasodilation: a review of nervous and biomechanical signals

Iliodromiti S et al (2010): Methyldopa in clinical practice

One solution is to create stable derivatives that can be absorbed into the skin, convert there to AA and do all the magic AA is proven to do (which is being an antioxidant, a collagen booster, and a skin brightener)

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Li Y, Liu J, Ma X, Bai X