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Copper can raise an enzyme called MMP-1, and MMP-1 breaks collagen down

Once in the intestine, the body can make the most use out of the Glutathione by assisting the liver in eliminating toxins

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J Immunol 143:197481 Yan Z, Garg SK, Banerjee R (2010) Regulatory T cells interfere with glutathione metabolism in dendritic cells and T cells

Claims that either compound is "safe for human use" are not supported by adequate clinical evidence