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You still need morning cortisol for alertness

While individual sensitivity varies, caffeine has a half-life of approximately 5 to 6 hours, meaning half of the caffeine from an afternoon coffee remains in your system at bedtime

Pro Tips: Take at the same time each day for consistency

Furthermore, cecal ligation and perforation could lead to sepsis and damage the liver and kidney of SD rats, and L-theanine had a significant inhibitory effect on this kind of liver and kidney injury in a dose-dependent manner (91)

Yes, many protocols combine these treatments